✦ LIBER ✦

Chemiionization and chemiluminescence in the reaction of SiH4 with active nitrogen

✍ Scribed by O. Horie; P. Potzinger; B. Reimann

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 551 KB
Volume: 129
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80202-0

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✦ Synopsis

The reaction of SiH4 with active nitrogen in a discharge-flow system was found to produce strong chemiionization besides the well-known SiN* and Si* chemiluminescences. In the presence of a large initial excess of N atoms, both N and SiH4 disappeared completely in the course of the reaction. Addition of as little 02 as 10" cms3 was sufficient to quench the chemiluminescence and suppress chemiionization completely. A mechanism explaining the experimental findings has to include a slow initiation step followed by a branched chain.

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