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Formation of nitric oxide from nitrous acid in ischemic tissue and skin

✍ Scribed by Anthony R. Butler; John H. Ridd

Book ID
116789866
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
144 KB
Volume
10
Category
Article
ISSN
1089-8603

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Oxidation of benzyl alcohols by nitrous
Oxidation of benzyl alcohols by nitrous and nitric acids in strong sulfuric acid media
✍ David S. Ross; Chee-Liang Gu; Georgina P. Hum; Ripudaman Malhotra πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 505 KB

We have studied the oxidation of benzyl alcohols by nitrous and nitric acid in sulfuric acid media. The oxidation by nitrous acid is rapid and has an activation energy of 10.6 -t 0.8 kcal mol-'. A Hammett plot of logkp vs. u -is linear with a p value of -1.4. The oxidation by nitric acid in sulfuric