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Formation of Metallophosphenium Cluster Complexes: Synthesis and Structure of Cp(Ph)[N(SiMe3)2]

✍ Scribed by Reisacher, Hans-Ulrich ;Duesler, Eileen N. ;Paine, Robert T.


Publisher
Wiley (John Wiley & Sons)
Year
1996
Tongue
English
Weight
335 KB
Volume
129
Category
Article
ISSN
0009-2940

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Reaction of cupferron [NH 4 L, L = PhN(O)NO -] with tin(IV), complex 2. The tin centers are heptacoordinated in a pentagonal bipyramidal geometry in the dimeric complex 3. diphenyltin(IV) and dimethyltin(IV) halides yields the cupferronato complexes SnL 4 (1), Ph 2 SnL 2 (2) and These complexes inco