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Terminal Borylene Complexes as a Source for the Borylene B−N(SiMe3)2: Alternative Synthesis and Structure of [(OC)5Cr=B=N(SiMe3)2]

✍ Scribed by Holger Braunschweig; Miriam Colling; Carsten Kollann; Hans G. Stammler; Beate Neumann

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 84 KB
Volume: 40
Category: Article
ISSN: 0044-8249
DOI: 10.1002/1521-3773(20010618)40:12<2298::aid-anie2298>3.0.co;2-e

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Terminale Borylenkomplexe als Quelle für

Terminale Borylenkomplexe als Quelle für das Borylen B−N(SiMe3)2: alternative Synthese und Struktur von [(OC)5Cr=B=N(SiMe3)2]

✍ Holger Braunschweig; Miriam Colling; Carsten Kollann; Hans G. Stammler; Beate Ne 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 82 KB

Triphospholes as 2e and 4e donors: Synth

Triphospholes as 2e and 4e donors: Synthesis and structural characterization of the 1,2,4-triphosphole complexes η1-trans-[PtCl2(PEt3)(P3C2Bu3.0.CO;2-H/asset/equation/tex2gif-stack-1.gif?v=1&t=h5m61cg7&s=fa3a6bf97af99c538117b88f2890f7c6562d34b9" class="inlineGraphic">CH(SiMe3)2] and η1-η1-trans-[PtCl2(PEt3)2}2(μ-P3C2Bu3.0.CO;2-H/asset/equation/tex2gif-stack-2.gif?v=1&t=h5m61cg7&s=7fb7c40667376fc773adea0fb5af23d3be67ce36" class="inlineGraphic">CH(SiMe3)2]

✍ Vinicius Caliman; Peter B. Hitchcock; J. F. Nixon 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 376 KB 👁 2 views

The first examples of g 1 -complexes of 1,2,4-triphospholes are reported in which the ring acts as a 2e and a 4e donor.