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Synthesis, Structure, and Reactivity of [Cp2Ti(HBcat)(PMe3)]: A Monoborane σ Complex

✍ Scribed by Clare N. Muhoro; Prof. Johan F. Hartwig


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
417 KB
Volume
36
Category
Article
ISSN
0044-8249

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Addition of stannylene [{(SiMe 3 ) 2 CH} 2 Sn:] (2) to the unbridged water results in the cleavage of an Ni-Sn bond and subsequent opening of the cluster cage of 3 to form the trinuclear homobimetallic Ni-Ni bond of [{PEt 3 Ni(η 5 -Cp)} 2 ] (1) gives the heterobimetallic, tetranuclear compound [{{(S