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Formation of Macrocycles via Ring-Closing Olefin Metathesis

✍ Scribed by Lee, Choon Woo; Grubbs, Robert H.

Book ID
121201113
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
65 KB
Volume
66
Category
Article
ISSN
0022-3263

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Synthesis of macrocyclic lactams and lac
Synthesis of macrocyclic lactams and lactones via ring-closing olefin metathesis
✍ William P.D. Goldring; AndrΓ©S. Hodder; Larry Weiler πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 254 KB

## A&Wrack Lactones and lactams 4-6 were synthesized from a series of acyclic dienes 1-3 via ringclosing olefin metathesis, as shown in equation 1. The geometry of the resulting double bond was determined, and the UZratios compared to values from molecular mechanics calculations.