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Formation of intermediate dianions in the flash photolysis of pyrenide radical anions in tetrahydrofuran

✍ Scribed by Kjell-Åke Engdahl; Göran Rämme

Book ID
103016671
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
349 KB
Volume
41
Category
Article
ISSN
0009-2614

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✦ Synopsis

Flash photolysis of soWions of alkali pyrenide salts (m?, M> in THF yields e, M+ pairs, which react with ITS to give pyrenide dimions (~'3. The rate constants for the reactions e-

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The flash-photolysis of sodium pyrenide
The flash-photolysis of sodium pyrenide in tetrahydrofuran. On the photo-oxidation process and on the existence of sodium atoms NaO
✍ L.J. Giling; J.G. Kloosterboer 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 546 KB

Evidence IS gvcn that the y~clds ot photoculdatmn for free pyrenc amens (n-) and for xuons sssoclated %tth SOdlum cdtlons(n-Na+) m hquld THF and THP xe connected to the cffectlvc threshold values for the pnoto--ronlUtton of free and associated pyrenc anlons Our cxpermmcntal results mdlcate that the