MECHANISM OF FORMATION OF FORMALDEHYDE IN THE FLASH PHOTOLYSIS OF METHYL FORMATE
β Scribed by S. L. N. G. Krishnamachari
- Book ID
- 114892039
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 210 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0031-8655
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π SIMILAR VOLUMES
The production o f C l 0 0 and C10 radicals following the flash photolysis of chlorine + oxygen mixtures has been studied. For the mechanism the following kinetic parameters were measured: and k:,/c(C100; 250 nm) = 9.7 x 105 cm/sec. Then h:3 = 5.9 X lo9 l/mol.sec, h2 = 1.0 X 10" limol-sec, and t(C
The photolysis of phenylazotriphenyl methane (PAT) in dichloromethane and acetonitrile solution at and at 23Β‘C results in the j inc \ 347 nm formation of triphenyl methyl (trityl) radicals and trityl ions. The quantum yields in dichloromethane solution are and Trityl '(Ph ions are assumed to be for