The flash-photolysis of sodium pyrenide in tetrahydrofuran. On the photo-oxidation process and on the existence of sodium atoms NaO

✍ Scribed by L.J. Giling; J.G. Kloosterboer

• Book ID: 103010385
• Publisher: Elsevier Science
• Year: 1973
• Tongue: English
• Weight: 546 KB
• Volume: 21
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(73)80030-2

✦ Synopsis

Evidence IS gvcn that the y~clds ot photoculdatmn for free pyrenc amens (n-) and for xuons sssoclated %tth SOdlum cdtlons(n-Na+) m hquld THF and THP xe connected to the cffectlvc threshold values for the pnoto--ronlUtton of free and associated pyrenc anlons Our cxpermmcntal results mdlcate that the phenomena observed by F'rsher and Ramme after flAsh-photolysls of sodium pyrenlde in THF wluch hake Icd to the postulation of trx&len: sodturn atoms Na" may bc interpreted as bemg caused by benzene or tcluenc negJtlvc Ions