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Formation of hot hexafluorobenzene in the 193 nm photolysis

✍ Scribed by T. Ichimura; Y. Mori; N. Nakashima; K. Yoshihara

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 518 KB
Volume: 104
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)80023-8

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✦ Synopsis

Time-resolved absorption spectra of hesafluorobenzene vapor have been observed with ArF laser (193 nm) exitation. The initial intermediate is posrulated to be due to HFBi(S,) (hot he\afluorobenzene with internal energ of 639 kJ/mol) because the transient spectrum can be simulated as part of the S, ('E,,) + So transition at 3050 I<.

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