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formation of electronically excited NH2(2A1, v2 ⩽ 15) by the reaction between H and HN3

✍ Scribed by O. Kajimoto; T. Kawajiri; T. Fuemo


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
329 KB
Volume
76
Category
Article
ISSN
0009-2614

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✦ Synopsis


The reaction between hydrogen atoms and hydrogen azide has been studied by the discharge flow method. Emissions from NH$AIL NH('Y and NH?fl) uere observed.

The NH,('AI) radical was highly excited in its ribrational states.

Dependence of the emission intensity on reactant concentrations was examined for both NH,('A,)

and NH(%) emission_ The results suggest that the NHJ'A,) is formed directly by reaction between H and HN,_ The eleclronically -cited NH('TI is probably produced by the reaction H+N,.


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We thank the European Commission through the HYDROCHEM program (contract HPRN-CT-2002-00176) for support of this work. M.B. thanks the Spanish Ministerio de Educación y Ciencia for a postdoctoral fellowship.