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Formation of Diazo Compounds on Decomposition of 2,3-Diazabicyclo[3.1.0]hex-2-enes:[3+2]-Cycloreversions

✍ Scribed by Dr. Manfred Schneider; Bernd Csacsko


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
316 KB
Volume
16
Category
Article
ISSN
0044-8249

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✦ Synopsis


Table 1. Selected physical properties of ( 5 a ) and (56) "C-NMR (in CDCl3, T M S internal) c-1 109.2 C-CN 97.4, 98.9, 102.0 c-4 108.9 c -5 c-1 ' 124.5 c -2 , c-3' 131.1 IR ( K B r ) [cm-'1 C=N 2210 Cyclopropene [5] 1898, 1550 UV(CH3CN) [ n m l (log&) 240 (4.61), 278 (4.23) 'H-NMR (100 MHz, CDClj, T M S internal) 4-H 6.78 (1 H, s) 5-H 109.9 97.7, 101.7, 102.5 105.1 124.8


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