Formation of ·CH2OC(O−)CR2 distonic radical anions by the reaction of O−· with dimethyl glutarates
✍ Scribed by E. A. Stemmler; C. Segovis
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 99 KB
- Volume
- 36
- Category
- Article
- ISSN
- 1076-5174
- DOI
- 10.1002/jms.160
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Pulsed laser photolysis/laser-induced fluorescence (LIFI is utilized to measure absolute rate constants of CH radical reactions as a function of temperature and pressure. Multiphoton dissociation of CHBr, at 266 nm is employed for the generation of C H (X'I1) radicals. The C H radical relative conce
## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215–340 nm. By scaling to σ(CH~3~O~2~)~240 nm~ = (4.24 ± 0.27) × 10^−18^, the following absorption cross sections were determined: σ(HO~2~)~240 nm~ = 1.29 ± 0
## Abstract The reaction of O(^1^__D__) with CH~4~ was studied to determine the efficiency of H~2~ production in a direct process, and it was found to be 0.11 ± 0.02. Thus the two channels which account for all of the reaction between O(^1^__D__) and CH~4~ in the gas phase are equation image
## Abstract The fast flow method with laser induced fluorescence detection of CH~3~C(O)CH~2~ was employed to obtain the rate constant of __k__~1~ (298 K) = (1.83 ± 0.12 (1σ)) × 10^10^ cm^3^ mol^−1^ s^−1^ for the reaction CH~3~C(O)CH~2~ + HBr ↔ CH~3~C(O)CH~3~ + Br (1, −1). The observed reduced react