Formation of a Dewar-Anisole by Bicyclopropenyl Rearrangement
β Scribed by Dr. Robert Weiss; Dipl.-Chem. Steffen Andrae
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 246 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
β¦ Synopsis
would be expected to preponderate very largely[Ig1, which accords with the experiment (see above). According to Scheme 2 the same situation should occur on Ag'-catalysis since there (13) [(I.?a)] is again postulated as intermediate: the almost identical o/p-ratio (see Table 1) is visible confirmation thereof.
π SIMILAR VOLUMES
During recent investigations on the scope of a new glycal synthesis\*, an unusual isomerisation of 3,6-anhydro-5-deoxy-l,2-O-isopropylidene-cu-D-xylo-hex-5;enofuranose2 (1) was observed; 1 was described previously as the sole product of base-promoted eliminations of 3,6-anhydro-S-deoxy-5-iodo-1,2-O-