𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Cope rearrangement of a bicyclopropenyl

✍ Scribed by W.H. de Wolf; I.J. Landheer; F. Bickelhaupt

Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
172 KB
Volume
16
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Formation of a Dewar-Anisole by Bicyclop
Formation of a Dewar-Anisole by Bicyclopropenyl Rearrangement
✍ Dr. Robert Weiss; Dipl.-Chem. Steffen Andrae πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 English βš– 246 KB

would be expected to preponderate very largely[Ig1, which accords with the experiment (see above). According to Scheme 2 the same situation should occur on Ag'-catalysis since there (13) [(I.?a)] is again postulated as intermediate: the almost identical o/p-ratio (see Table 1) is visible confirmatio

An enolate-accelerated cope rearrangemen
An enolate-accelerated cope rearrangement
✍ Paul A. Wender; Robert J. Ternansky; Scott McN. Sieburth πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 256 KB

The first example of an enolate accelerated Cope rearrangement is described along with its importance in the rearrangement of S-alkoxy-deca-1,3,7,9\_tetraenes. We recently introduced a macroexpansion method' for the synthesis of large ring compounds, exemplified by the conversion of 1 into 4(Scheme