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A New Mechanistic Concept for the Bicyclopropenyl Rearrangement

โœ Scribed by Dr. Robert Weiss; Dipl.-Chem. Steffen Andrae

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
320 KB
Volume
12
Category
Article
ISSN
0044-8249

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## Abstract Roark and Peddle first observed that, when not trapped, Me~2~Si๏ฃพSiMe~2~ underwent a series of rearrangements to give two major isomeric products: 1,1โ€dimethylโ€1,3โ€disilacyclobutane and 1,3โ€dimethylโ€1,3โ€disilacyclobutane. The widely accepted mechanism for this rearrangement was proposed