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Formation and Structure of Iodotrinitrosyliron, [Fe(NO)3I].

✍ Scribed by Wolfgang Beck; Armin Enzmann; Peter Mayer

Publisher
John Wiley and Sons
Year
2005
Weight
10 KB
Volume
36
Category
Article
ISSN
0931-7597

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The equilibrium constant for the reaction kl (1) NOS-+ HBr 2 Br-+ HNO, has been determined between 331 and 480'K using a variable-temperature flowing afterglow. These data give AH"(1) = -1.03 f 0.21 kcal/mol and AS"(1) = -4.6 f 1.0 cal/mol.'K. When combined with the known thermochemical values for H