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Formale Totalsynthese von (±)-Isocomen durch Anwendung der α-Alkinon-Cyclisierung

✍ Scribed by Giuseppe G. G. Manzardo; Martin Karpf; André S. Dreiding


Publisher
John Wiley and Sons
Year
1986
Tongue
German
Weight
764 KB
Volume
69
Category
Article
ISSN
0018-019X

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Anwendung der α-Alkinon-Cyclisierung: To
✍ Giuseppe G. G. Manzardo; Martin Karpf; André S. Dreiding 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 370 KB

**Application of the α‐Alkynone Cyclization: Total Synthesis of (±)‐Albene** A synthesis of the racemic form of the natural tricyclic hydrocarbon albene **(1)** from the __Diels‐Alder__ adduct **2** of tiglyl chloride and cyclopentadiene is described (24% yield). The key step **5→6** involves a the

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