State-of-the-art ab initio computations have been performed on the ground state of HN3 and CH3N3. The methods employed include Roothaan-Hartree-Fock molecular orbitals, single-and double-excitation configuration interaction, as well as modifiedcoupled-pair-functional approximations. The basis sets c
Force constants of hydrazoic acid and methyl azide
β Scribed by W.T. Thompson; W.H. Fletcher
- Publisher
- Elsevier Science
- Year
- 1966
- Weight
- 701 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0371-1951
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π SIMILAR VOLUMES
Seven b-type P nnd R branch rotational transitions and seven u-type @ branch transitions have been measured for the slightly asymmetric rotor H f4Ns in the microwave and millimeter wave regions. The information obtained from these transitions includes the rotational constant Ao = 610996.2 (6.0) MHz.
A single step procedure for the direct and regioselective synthesis of carbohydrate azides from unprotected sugars using hydrazoic acid under Mitsunobu conditions is reported. A series of mono-, di-, or triazido polyhydroxylated systems are described.