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Direct azidation of unprotected carbohydrates under Mitsunobu conditions using hydrazoic acid

✍ Scribed by Céline Besset; Stéphane Chambert; Bernard Fenet; Yves Queneau


Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
308 KB
Volume
50
Category
Article
ISSN
0040-4039

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✦ Synopsis


A single step procedure for the direct and regioselective synthesis of carbohydrate azides from unprotected sugars using hydrazoic acid under Mitsunobu conditions is reported. A series of mono-, di-, or triazido polyhydroxylated systems are described.


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