The callision-Induced depolarized Light xaltering spectrum of SF, is measured in Ihe frequency range O-100 cm-' at pressures 0111.6 IO 19 aim at 295 K. Inductd rotational Raman sc~~ering is presem but the magnitude 01 the dipole-oclopole polarizabiliry deduced depends markedly on the inwrmolecular p
Forbidden Raman bands of Sf6: collision induced Raman scattering
β Scribed by W. Holzer; R. Ouillon
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 488 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
received 26 November l973
The frequencies, relative scattering cross sections and depolarizations ratios of forbidden fundamental and overtone Raman bands have been measured for the first time in the gaseous state. The absolute scattering cross sections of the allowed bands of gaseous SF6 are given as well. The characteristic density dependence of the scattering cross sections of the forbidden fundamentals is explained in terms of collision induced Raman scattering. There is evidence for frame distortion of the molecules during the collision.
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