In a previous paper, we have presented experimental and theoretical results on the intensity of forbidden IR and Raman bands of CSz in liquid solutions. To reduce the disagreement observed on some Raman results, we consider changing the value of the derivative of the hyperpolarizability p with respe
Collision induced raman spectra of liquid CS2
โ Scribed by T.I. Cox; P.A. Madden
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 469 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The fineshapes of the Raman scattering from the "forbidden" Cz and rxu modes of liquid CS2 have been measured and compared with other "co&ion-induced" spectra. it is argued that the scattering is caused by the action of intermolecular fields arising from permanent moments on the vibrationally induced ~y~e~ola~sability of CS2.
๐ SIMILAR VOLUMES
received 26 November l973 The frequencies, relative scattering cross sections and depolarizations ratios of forbidden fundamental and overtone Raman bands have been measured for the first time in the gaseous state. The absolute scattering cross sections of the allowed bands of gaseous SF6 are given
Metastnble transitions in CS$ leading to S' + CS and CS++ S under electron impact on CS2 are reported. The predissociation processes able to explain the occurrence of these metastablc transitions are discussed. An interpretation of mrne fast dissociation processes is suggested.