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Follow the Protons: A Low-Barrier Hydrogen Bond Unifies the Mechanisms of the Aspartic Proteases

โœ Scribed by Northrop, Dexter B.

Book ID
127012036
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
99 KB
Volume
34
Category
Article
ISSN
0001-4842

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There are large differences between the acidity of the enol of the acyclic diketone, 2,4-pentanedione and those of two cyclic diketones, 1,3-cyclopentanedione and 1,3-cyclohexanedione. Computational studies have demonstrated that these differences are largely due to the strength of the internal low-