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A New Concept for the Mechanism of Action of Chymotrypsin: The Role of the Low-Barrier Hydrogen Bond †

✍ Scribed by Cassidy, Constance S.; Lin, Jing; Frey, Perry A.

Book ID
126874472
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
239 KB
Volume
36
Category
Article
ISSN
0006-2960

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There are large differences between the acidity of the enol of the acyclic diketone, 2,4-pentanedione and those of two cyclic diketones, 1,3-cyclopentanedione and 1,3-cyclohexanedione. Computational studies have demonstrated that these differences are largely due to the strength of the internal low-