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Fluxional behavior of coordinated propargyl cations [(μ-η2, η3-HC≡CCR1R2)Cp2M2(CO)4]+BF4−(M = Mo, W; R = H, Me) in solution

✍ Scribed by I. V. Barinov; V. A. Chertkov

Book ID: 106521098
Publisher: Springer
Year: 2008
Tongue: English
Weight: 151 KB
Volume: 57
Category: Article
ISSN: 1573-9171
DOI: 10.1007/s11172-008-0375-2

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## Abstract Internal rotation about the C‐2–C‐3 bond was observed in the ^13^C CP‐MAS NMR spectra of the solid complexes [M~2~(ηHC^1^C^2^C^3^Me~2~)(CO)~4~(ηC~5~H~5~)~2~]^+^ [BF~4~]^−^ where M = Mo or W.