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13C NMR spectra of coordinated propargyl cations [Cp2Mo2(CO)4(μ-η2,η3-(HC≡CCR1R2)]+BF4/−

✍ Scribed by I. V. Barinov; V. A. Chertkov

Book ID
111494748
Publisher
Allerton Press Inc
Year
2009
Tongue
English
Weight
138 KB
Volume
64
Category
Article
ISSN
0027-1314

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13C CP-MAS NMR spectra and fluxional beh
13C CP-MAS NMR spectra and fluxional behaviour of [M2(ηHCCCMe2)(CO)4(ηC5H5)2]+ [BF4]− (M = Mo, W) complexes in the solid state
✍ M. V. Galakhov; V. I. Bakhmutov; I. V. Barinov 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 180 KB

## Abstract Internal rotation about the C‐2–C‐3 bond was observed in the ^13^C CP‐MAS NMR spectra of the solid complexes [M~2~(ηHC^1^C^2^C^3^Me~2~)(CO)~4~(ηC~5~H~5~)~2~]^+^ [BF~4~]^−^ where M = Mo or W.