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Fluoroorganometallic chemistry: carbon-fluorine bond activation in perfluorometallacyclopentane complexes

✍ Scribed by Burch, Robert R.; Calabrese, Joseph C.; Ittel, Steven D.

Book ID
126405586
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
940 KB
Volume
7
Category
Article
ISSN
0276-7333

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## Abstract Monocoordinate nickel/__N__‐heterocyclic carbene complexes reveal unexpected reactivity towards aryl fluorides. Defluorination reactions were efficiently performed with a β‐hydrogen‐containing alkoxide (3 equiv.) in the presence of 3 mol % of [1:1] Ni(0)/IMes⋅HCl catalyst (IMes=1,3‐dime