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Catalytic Carbon-Fluorine Bond Activation with Monocoordinated Nickel-Carbene Complexes: Reduction of Fluoroarenes.

✍ Scribed by Sebastien Kuhl; Raphael Schneider; Yves Fort


Publisher
John Wiley and Sons
Year
2003
Weight
120 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Catalytic Carbon-Fluorine Bond Activatio
✍ Sébastien Kuhl; Raphaël Schneider; Yves Fort 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 63 KB 👁 1 views

## Abstract Monocoordinate nickel/__N__‐heterocyclic carbene complexes reveal unexpected reactivity towards aryl fluorides. Defluorination reactions were efficiently performed with a β‐hydrogen‐containing alkoxide (3 equiv.) in the presence of 3 mol % of [1:1] Ni(0)/IMes⋅HCl catalyst (IMes=1,3‐dime