Catalytic Carbon-Fluorine Bond Activatio
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Sébastien Kuhl; Raphaël Schneider; Yves Fort
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Article
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2003
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John Wiley and Sons
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English
⚖ 63 KB
👁 1 views
## Abstract Monocoordinate nickel/__N__‐heterocyclic carbene complexes reveal unexpected reactivity towards aryl fluorides. Defluorination reactions were efficiently performed with a β‐hydrogen‐containing alkoxide (3 equiv.) in the presence of 3 mol % of [1:1] Ni(0)/IMes⋅HCl catalyst (IMes=1,3‐dime