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Catalytic Carbon-Fluorine Bond Activation with Monocoordinated Nickel-Carbene Complexes: Reduction of Fluoroarenes

✍ Scribed by Sébastien Kuhl; Raphaël Schneider; Yves Fort

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 63 KB
Volume: 345
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.200390036

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✦ Synopsis

Abstract

Monocoordinate nickel/N‐heterocyclic carbene complexes reveal unexpected reactivity towards aryl fluorides. Defluorination reactions were efficiently performed with a β‐hydrogen‐containing alkoxide (3 equiv.) in the presence of 3 mol % of [1:1] Ni(0)/IMes⋅HCl catalyst (IMes=1,3‐dimesitylimidazol‐2‐ylidene).

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