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Fluoride induced isomerization of cobalt diene complexes

✍ Scribed by Joseph M. O'Connor; Ming-Chou Chen; Arnold L. Rheingold

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
211 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

A metal-mediated addition of two carbenes across an alkyne is employed for the synthesis of (2-phenylsulfonyl)-1,3-dienes. Control of diene stereochemistry is achieved through an unprecedented fluoride-catalyzed isomerization of the cobalt diene intermediates.

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