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Skeletal isomerization of dienes by nickel hydride complexes

โœ Scribed by L.W. Gosser; G.W. Parshall

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
216 KB
Volume
12
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Although positional lsomerizatlon of olefins is well studied and skeletal lsomerizatlon of strained hydrocarbons is receiving much current attention,2 there have been few reports of skeletal lsomerizatlon of unstrained ole-Pins by homogeneous catalysts. One of the most interesting examples Is the isomerization of u-l,&hexadlene (l_) to trans-2-methyl-1,3-pentadlene (5) catalyzed by a mixture of (n-Bu3 P)2NlC12 and (i+_~)~AlCl.~~ The reports of this reaction M. L. H. Green, M. Nehme' , and G. Wilkinson, Chem. Ind., 11.36 (1960).

(10) M. L. H. Green and T. SaitO, Chem. Commun., 208 (1969).

(11) F. Carlatl, R. Ugo, and F. Bonatl, Inorn. Chem., 2, 1128 (1966).

(12) C. A. Tolman, W. C. Seidel, and L. W. Goaaer, to be published.

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