𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Fluorescence Excitation Spectrum of a 2Π3/2–2Π3/2 Transition of NiF

✍ Scribed by Yang Chen; Jin Jin; Changjin Hu; Xueliang Yang; Xingxiao Ma; Congxiang Chen


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
69 KB
Volume
203
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis


In this study, a supersonic beam of NiF was produced by the reaction of SF 6 with a dc discharge-sputtering source of nickel atoms. The laser-induced fluorescence excitation spectrum of a 2 ⌸ 3/2 -2 ⌸ 3/2 transition has been recorded in the range of 500 -520 nm and rotational structure of 506.5-nm band analyzed under the 30 K rotational temperature. Our data are consistent with a 2 ⌸ 3/2 ground state for NiF. The lifetime of this band is measured.


📜 SIMILAR VOLUMES


Laser-Induced Fluorescence of a 2Π3/2-2Σ
✍ A. Bouddou; C. Dufour; B. Pinchemel 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 271 KB

Taking advantage of an improved experimental method. a new \({ }^{2} \mathrm{I}_{3 / 2}-^{-2} \mathrm{\Sigma}\left(18145 \mathrm{~cm}^{-1}\right)\) transition of \(\mathrm{NiF}\) has been rotationally analyzed. It gives a quantitative confirmation of the energy-level diagram published recently (C. D

Line Positions and Intensities in the Fu
✍ J.Y. Mandin; V. Dana; L.H. Coudert; M. Badaoui; F. Leroy; M. Morillonchapey; R. 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 467 KB

Using Fourier transform spectra, absolute line positions and intensities have been measured in the \({ }^{2} \Pi_{1 / 2}{ }^{2} \Pi_{3 / 2}\) and \({ }^{2} \Pi_{3 / 2}{ }^{2} \Pi_{1 / 2}\) forbidden subbands of the vibrational \(1 \leftarrow 0\) fundamental band of nitric oxide. To retrieve accurate

Exchange reactions in selectively excite
✍ Richard M. Lum; Kenneth B. McAfee Jr. 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 484 KB

Laser-controlled bimolecular isotopic exchange reactions in bromine leading to alterations in natural isotopic abundance ratios have been directly observed using lasermodulated molecular beams and mass analysis. Several instances of selective excitation and subsequent rapid isotope exchange are obse

Fast Ion Beam Laser Spectroscopy of13CO+
✍ N. Varfalvy; P. Lafleur; M. Larzillière 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 240 KB

Laser induced fluorescence of a fast ion beam has been applied to 13 CO / 2 for its (0, 0, 0) A ˜2P u -(0, 0, 0) X ˜2P g UV electronic transition. The high resolution (0.005 cm 01 ) of the FIBLAS method, due to a highly reduced Doppler broadening, allows us to evaluate the isotopic shift, to appreci

High-Resolution Study of theX22Π3/2→X12Π
✍ K. Ziebarth; K.D. Setzer; O. Shestakov; E.H. Fink 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 290 KB

The near-infrared emission spectra of the X 2 2 ⌸ 3/2 3 X 1 2 ⌸ 1/2 fine structure transitions of PbF and PbCl have been investigated by high-resolution Fourier-transform spectrometry. Despite the large fine structure splitting, the bands can be equally well analyzed with Hund's case (a) or case (c)