The X(1)(2)Pi(3/2) and X(2)(2)Pi(1/2) potential energy curves of the FO free radical have been determined from a fit to the available high-resolution spectroscopic data. The data set spans the vibrational states v = 0-7 and includes X(2)(2)Pi(1/2) <-- X(1)(2)Pi(3/2) fine-structure transitions. The d
Line Positions and Intensities in the Fundamental 1 ← 0 Forbidden 2Π1/2-2Π3/2 and 2Π3/2-2Π1/2-Subbands of Nitric Oxide
✍ Scribed by J.Y. Mandin; V. Dana; L.H. Coudert; M. Badaoui; F. Leroy; M. Morillonchapey; R. Farrenq; G. Guelachvili
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 467 KB
- Volume
- 167
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
Using Fourier transform spectra, absolute line positions and intensities have been measured in the ({ }^{2} \Pi_{1 / 2}{ }^{2} \Pi_{3 / 2}) and ({ }^{2} \Pi_{3 / 2}{ }^{2} \Pi_{1 / 2}) forbidden subbands of the vibrational (1 \leftarrow 0) fundamental band of nitric oxide. To retrieve accurate results from the spectra, the hyperfine structure was carefully taken into account. From the measured line intensities, the vibrational transition dipole moment, as well as the Herman-Wallis cocfficients, has been determined for the studied subbands. (c) 1994 Academic Press, Inc.
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