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Transition Moments between1Δg,1Πg, and1ΠuStates of the H2Molecule

✍ Scribed by L. Wolniewicz

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
197 KB
Volume
180
Category
Article
ISSN
0022-2852

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✦ Synopsis

Electronic transition moments are computed for dipole transitions between the C and D 1 P u , I and R 1 P g and J and S 1 D g states of the hydrogen molecule for internuclear distances R √ [1, 15] bohr. The character of the wavefunctions at large internuclear distances is investigated. It is shown that in the D and R states the asymptotic configurations are strongly mixed for R £ 15 bohrs. The S state has mixed character even at R Å 40 bohr.

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