Phosphate can be determined spectrophotometrically at 560 nm based on the reaction of 12-molybdophosphate and Crystal Violet using flow-injection analysis. The carrier stream was 0.5% (w/v) poly(viny1 alcohol) solution and the reagent streams were 0.1 M sodium molybdate, 5 x 10m4 M Crystal Violet an
Flow-injection spectrophotometric determination of aluminium in water with pyrocatechol violet
✍ Scribed by Oddvar R∅yset
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 455 KB
- Volume
- 185
- Category
- Article
- ISSN
- 0003-2670
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✦ Synopsis
Optimum conditions for the adaptation of the spectrophotometric pyrocatechol violet method for aluminium to a flow-injection system are described. The detection limit is 3 pg Al 1-l and calibration graphs are linear up to 3 or 10 mg 1-l (with 2OOql or lo-r1 injection loops, respectively). The relative standard deviation is <2% at 0.1 mg Al 1-l. Potential interferences of 40 common inorganic ions and of 20 organic substances, including fulvic acid, are reported. With the use of conventional masking agents and predigestion of samples with high organic content, the method is suitable for determining total aluminium in natural waters.
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