We proposed a simple flow-injection spectrophotometric procedure for the determination of yttrium using Arsenazo III and optimized various conditions (pH for color formation and sample, buffer systems, Arsenazo III concentration, injection volume, flow-rate, and mixing coils). The calibration was li
Flow-injection spectrophotometric determination of palladium with DCS-arsenazo
β Scribed by Xing-Cun He; Ya-Qi Cai; Zhi-De Hu
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 300 KB
- Volume
- 256
- Category
- Article
- ISSN
- 0003-2670
No coin nor oath required. For personal study only.
β¦ Synopsis
A flow-inJectIon spectrophotometnc method for the determmatlon of palladmm mvoives the measurement of the absorbance of the pallachum complex with DCS-arsenazo at 635 nm The cahbratlon graph IS hnear over the range O-8 0 pg ml-' The detectIon hrnlt IS 0 05 pg ml-1 The sample throughput IS 90 h-' with lOO-~1 sample uqecttons The proposed method has been apphed to the determmatlon of palladmm m metallurgical samples wIthout prehmmary separation
π SIMILAR VOLUMES
A flow-injection spectrophotometric method for the determination of hydrazine is described. The method is based on the inhibitory effect of hydrazine on the reaction of thionine with nitrite in acidic media. The decolorization of thionine by the reaction with nitrite was used to monitor the reaction
The indirect spectrophotometric determination of 0.8-7.2 ppm calcium in the presence of magnesium, phosphate and sulphate by flow injection analysis (f.i.a.) is described. The method is based on the exchange reaction between the calcium and the zinc complex of ethylene glycol-bis(2aminoethylether)te
A flow-injection spectrophotometric method for the determination of adrenaline and isoprenaline, based on the reaction with metaperiodate, is described. The calibration graphs are linear up to 2X 10e4 M. Flow injection allows the measurement of 120 samples per hour. The method was successfully appli
A flow-injection method using spectrophotometric detection at 325 nm, is proposed for the determination of carbimazole or methimazole. The procedures are based on the formation of yellow complexes between these antithyroid drugs and Pd(II) in 0.5 M HCl. Methimazole or carbimazole are determined over