Flavonol 3-O-robinobiosides and 3-O-(2″-O-α-rhamnopyranosyl)-robinobiosides from Sesuvium portulacastrum
✍ Scribed by Wannaporn Disadee; Chulabhorn Mahidol; Poolsak Sahakitpichan; Somkit Sitthimonchai; Somsak Ruchirawat; Tripetch Kanchanapoom
- Book ID
- 108283573
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- French
- Weight
- 274 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
Syntheses of the title glycosides are described. The critical O-glycosylations were carried out in the presence of boron trifluoride etherate with a high degree of alpha-selectivity.
Pseudomonas aeruginosa / Rhamnolipid / One-pot two-step glycosylation / Chemoselectivity / Esterification / Carbohydrates N-iodosuccinimide/triflic acid mediated one-pot two-step hydroxydecanoate (13) gave rhamnolipid 17. The latter was transformed in five steps into the title compound 2. glycosylat