Flash photolysis of ammonia in the presence of oxygen UTIS studied using the intmcwity Iaser spectroscopy technique. The reaction NH2 + 02 was demonstrated to be of no importance and a value of k6 < 1.5 X 10-t' cm3/molecule s was estimated-Accelerating NH~ decay with oxygen addition is due to :he re
Flash Photolysis and Fluorescence of Ammonia
β Scribed by W. Groth
- Publisher
- John Wiley and Sons
- Year
- 1963
- Tongue
- English
- Weight
- 148 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
The reaction of Cl atoms with chlorine nitrate has been reinvestigated by flash photolysis resonance fluorcsccnce over the temperature range 220-296 I;. The new results can be tit to the Arrhenius expression kr = 7.3 X 10-r\* esp(165/7I cm3 molecule-' s-l, in good agreement with another recent study
## Abstract The flash photolysis resonance fluorescence technique has been used to measure the rate constant for the reaction equation image over the temperature range of 250β370 K. The present results are in excellent agreement with three very recent studies, and the combined data set can been u
## Abstract Flash photolysis of __s__βtrinitrobenzene (TNB) aerated solutions in alcohols generates a transient species with absorption maxima at 430 and 510 nm. The yield of the transient is a function of oxygen concentration, and its rate of formation is viscosity dependent. In deaerated solution
## Abstract Flash photolysis of 2,4,6βtrinitrotoluene solutions (TNT) indicates a photochemically induced isomerization leading to the aciβquinoid isomer magnified image with an absorption maximum at 460 nm in nonpolar solvents, or the conjugate base magnified image of the aciβquinoid isomer with a
Rate constants for the reaction of OH radicals in a homogeneous gas phase reaction with dhnethyl sulfide have been determined using the flash photolysis resonance fluorescence technique over the temperature range 273400 K. The data (combined with the results of another recent study) can be fit to th