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Flash Photolysis of 2,4,6-Trinitrotoluene Solutions

✍ Scribed by K. Suryanarayanan; C. Capellos

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
480 KB
Volume
6
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

Flash photolysis of 2,4,6‐trinitrotoluene solutions (TNT) indicates a photochemically induced isomerization leading to the aci‐quinoid isomer magnified image with an absorption maximum at 460 nm in nonpolar solvents, or the conjugate base magnified image of the aci‐quinoid isomer with absorption maxima at 500, 540, and 630 nm in polar solvents. Both species, the quinoid isomer and the conjugate base, have transient existence and their identification was based on detailed spectroscopic and kinetic studies presented here. The magnitude of the negative charge on the transient conjugate base was determined with salt effect experiments and found to be equal to unity.

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