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First X-ray structure of hexaamminecobalt(III) salt with complex fluoroanion: Synthesis and characterization of [Co(NH3)6]X·SiF6·nH2O, where X = Cl, Br, I and NO3 and crystal structure of [Co(NH3)6]Cl·SiF6·2H2O

✍ Scribed by Raj Pal Sharma; Ritu Bala; Rajni Sharma; Urszula Rychlewska; Beata Warżajtis


Book ID
108170382
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
403 KB
Volume
126
Category
Article
ISSN
0022-1139

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Hexaamminecobalt(III) complexes as multi
✍ Ritu Bala; Raj Pal Sharma; Upendra Sharma; Andrew D. Burrows; Kevin Cassar 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 607 KB

The compounds [Co(NH 3 ) 6 ]Br 2 (BF 4 ) 1 and [Co(NH 3 ) 6 ]Cl 2 (HC 2 O 4 )AEH 2 O 2 have been prepared and structurally characterised. The two crystallographically independent cations in 1 are involved in different hydrogen bonding patterns, with one forming predominantly NAHÁ Á ÁF interactions w