A tricyclic sesquiterpenoid, valeriananoid A 1, has been synthesized via domino Michael reaction of oxophorone 4 and subsequent 6-endo-trig cyclization of a ketyl radical as key steps.
✦ LIBER ✦
First total synthesis of (±)-sepicanin A
✍ Scribed by Jin Hui Yang; Wen Qian Huang; Jun Shan Luo; Dong Dong Guo; Yu Heng Zhang; Hong Jun Li
- Book ID
- 113523304
- Publisher
- Chinese Electronic Periodical Services
- Year
- 2012
- Tongue
- English
- Weight
- 178 KB
- Volume
- 23
- Category
- Article
- ISSN
- 1001-8417
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
First total synthesis of valeriananoid A
✍
Hisahiro Hagiwara; Akihiro Morii; Yu Yamada; Takashi Hoshi; Toshio Suzuki
📂
Article
📅
2003
🏛
Elsevier Science
🌐
French
⚖ 142 KB
First Total Synthesis of Bengazole A†
✍
Mulder, Roger J.; Shafer, Cynthia M.; Molinski, Tadeusz F.
📂
Article
📅
1999
🏛
American Chemical Society
🌐
English
⚖ 66 KB
First total synthesis of pyrrolam A
✍
Yutaka Aoyagi; Tomofumi Manabe; Akihiro Ohta; Teruo Kurihara; Gui-Lin Pang; Take
📂
Article
📅
1996
🏛
Elsevier Science
🌐
French
⚖ 386 KB
First total synthesis of (+)-crassalacto
✍
V. Shekhar; D. Kumar Reddy; V. Suresh; D. Chanti Babu; Y. Venkateswarlu
📂
Article
📅
2010
🏛
Elsevier Science
🌐
French
⚖ 245 KB
A simple and highly efficient first total synthesis of cytotoxic (+)-crassalactone A starting from (R)-mandelic acid is described. The strategy involves the osmium tetroxide-catalyzed cis-hydroxylation and the stereoselective addition of ethyl lithiopropiolate to a chiral aldehyde intermediate as ke
First total synthesis of (+)-Carainterol
✍
Kaiqing Ma; Chunbo Zhang; Mingming Liu; Yong Chu; Lu Zhou; Changqi Hu; Deyong Ye
📂
Article
📅
2010
🏛
Elsevier Science
🌐
French
⚖ 387 KB
The first, stereospecific, and elegant synthesis of the natural product (+)-Carainterol A was developed by using the Robinson annulation reaction as a key step to build the eudesmane skeleton.
First total synthesis of strongylodiol A
✍
J.S Yadav; Rajesh Kumar Mishra
📂
Article
📅
2002
🏛
Elsevier Science
🌐
French
⚖ 57 KB