✦ LIBER ✦

First total synthesis of valeriananoid A

✍ Scribed by Hisahiro Hagiwara; Akihiro Morii; Yu Yamada; Takashi Hoshi; Toshio Suzuki

Book ID: 104253004
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 142 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)00064-9

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✦ Synopsis

A tricyclic sesquiterpenoid, valeriananoid A 1, has been synthesized via domino Michael reaction of oxophorone 4 and subsequent 6-endo-trig cyclization of a ketyl radical as key steps.

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