First synthesis of optically active azamacrolides
β Scribed by B Venkateswara Rao; V Satish Kumar; M Nagarajan; D Sitaramaiah; AV Rama Rao
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 195 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Simple optically active selenoxides (5-11 $e.e.) were prepared resolution procedure and were demonstrated to be configurationally unstable as catalyzed achiral hydrate formation.
## Abstract (β)β(__S__)β and (+)β(__R__)β3βmethylcyclopentene (__1__) has been prepared in a stereochemically unambiguous synthesis. The (__S__)βconfiguration for (β)β__1__ was confirmed by correlation with (β)β(__S__)β1βmethylindane.
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Optically active 1-substituted taurines, a type of important sulfur analogues of naturally occurring amino acids, and their N-benzyloxycarbonyl-protected derivatives were synthesized from the corresponding optically active Ξ²-amino secondary alcohols in three steps via N-protection with benzyl chloro