First Palladium-Catalyzed Aziridination Reaction of Amino Allenes
β Scribed by Ohno, Hiroaki; Toda, Ayako; Miwa, Yoshihisa; Taga, Tooru; Osawa, Eriko; Yamaoka, Yumiko; Fujii, Nobutaka; Ibuka, Toshiro
- Book ID
- 120351217
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 49 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0022-3263
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The authors gratefully acknowledge the "Region RhBne-Alpes" for its financial support. REFERENCES a) WALSH,C. ; Tetrahedron, 1982, 2 , 871. b) ANGST,C.
Substituted allenes are selectively obtained in good yields from the reaction of Grignard reagents with propargylic or allenic halides in the presence of catalytic amounts of palladium chloride, triphenylphosphine and diisobutyl aluminum hydride, in