First observation of the SeO+ emission spectrum. Vibrational analysis of the A2Π-X2Π system
✍ Scribed by J.A. Coxon; S. Naxakis; A.Brian Yamashita
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 314 KB
- Volume
- 117
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The low-resolution emission spcctrurn of the selenium monoxide cation, S&+. excited in Lhe reaction 01 discharged helium with SeOC12. has been recorded from 15000 lo 25500 cm-'. Thirty-tivc bandheads have been tigned LO Ihe A'II-X211 system of SeO+_ Vibrational W~SL~IMS of the new A'll and X21T slates have been estiated from least-squares Z~LS of the measured head positions.
📜 SIMILAR VOLUMES
The A \*l-I,-X \*IIs electronic emission spectrum of I$ has been recorded at a low rotational temperature in a crossed molecular beam/electron beam apparatus. Six vibrational sequences with live or more members have been assigned to progressions in v', giving w: = 122 f 8 cm-', but a full vibrationa
Absolute wbratlonal quvltum numbers for the SO\*(A 2tt-X 2nr) emwon sysrcm hwc been dctrrmmcd by mc%urcment of gotope shrfts between S160\* and S180+ bands It has been found that the tentatwe u" values reported previously should be decreased by one vibrwond quantum number. The defimtc molecular cons