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The A 2Πu-X 2Πg emission spectrum of I2+

✍ Scribed by S.M. Mason; R.P. Tuckett

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
507 KB
Volume
160
Category
Article
ISSN
0009-2614

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✦ Synopsis

The A *l-I,-X *IIs electronic emission spectrum of I$ has been recorded at a low rotational temperature in a crossed molecular beam/electron beam apparatus. Six vibrational sequences with live or more members have been assigned to progressions in v', giving w: = 122 f 8 cm-', but a full vibrational analysis has not been possible. It is not known whether this is due to the relatively poor resolution ( z 5 cm-' ) at which the spectrum has been recorded or because the A *rI, state is perturbed in one or both spinorbit components. Existing data on the A state of 1: are reviewed.

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