The low-resolution emission spcctrurn of the selenium monoxide cation, S&+. excited in Lhe reaction 01 discharged helium with SeOC12. has been recorded from 15000 lo 25500 cm-'. Thirty-tivc bandheads have been tigned LO Ihe A'II-X211 system of SeO+\_ Vibrational W~SL~IMS of the new A'll and X21T sla
Vibrational analysis of the SO+ (A2Π−χ2Πr) emission system by an isotopic study
✍ Scribed by Isao Murakami; Masaharu Tsuji; Yukio Nishimura
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 385 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Absolute wbratlonal quvltum numbers for the SO*(A 2tt-X 2nr) emwon sysrcm hwc been dctrrmmcd by mc%urcment of gotope shrfts between S160* and S180+ bands It has been found that the tentatwe u" values reported previously should be decreased by one vibrwond quantum number. The defimtc molecular constants for the SO+(A 'tl. X ?lr) states are de[ermmrd and compared wth photoelectron spectroscopx daa
📜 SIMILAR VOLUMES
Twenty-seven bands of the \(A^{2} \mathrm{II}_{\mathrm{u}}-X^{2} \mathrm{II}_{\mathrm{B}}\) transition were recorded at high resolution using the velocity modulation technique in the visible region. A vibrational and rotational analysis is performed for the mixed isotopic species and improved molecu