𝔖 Bobbio Scriptorium
✦   LIBER   ✦

First example of the cycloaddition of a terminal phosphinidene across the RhRh bond of [Rh2(η5-C5Me5)2{η-(CO)2}. Crystal structure of [Rh2(η5- C5Me5)2(CO)2{MePW(CO)5}]

✍ Scribed by Florence A. Ajulu; Peter B. Hitchcock; François Mathey; John F. Nixon

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
176 KB
Volume
444
Category
Article
ISSN
0022-328X

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Synthesis and Structure of [(C5Me5)2M2Se
Synthesis and Structure of [(C5Me5)2M2Se5]: Formation of a μ,η2-Tetraselenide Ligand at the MM Double Bond of [(C5Me5)2M2(μ-CO)2)] (M Co, Rh)
✍ Prof. Dr. Henri Brunner; Walter Meier; Dr. Joachim Wachter; Dr. Bernd Nuber; Pro 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB 👁 1 views

65% 13 16 Scheme2. Reactionsof 1 ( X ' , X 2 = O ; a ) , 8 ( X ' , X ' = N -N H -T s ; b ) , 9 ( X ' , X'=N-NNa-Ts; c, d), and 10 ( X , = H , X2=Me--S0,; f). a) Al2O3. b) MeLi, EtzO, 0°C. c) 125°C. d) hv, THF, 20°C. e) Preparative gas chromatography, Carbowax, 160°C. f) KOtBu.