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Binuclear Binuclear complexes of rhodium or copper with pentamethylcyclopentadienyltricarbonyltungsten. Crystal structure of (η5−C5Me5)(CO)W(μ-CO)2Rh(PPh3)2

✍ Scribed by W.Edward Lindsell; Kevin J. McCullough; Sabine Plancq


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
775 KB
Volume
491
Category
Article
ISSN
0022-328X

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to the IR data structural proof is provided principally by the I3C-NMR spectrum (in C6D6) which, apart from signals of the phosphane-and cyclopentadienyl-carbon atoms, contains two doublets of doublets at 6=311.41 and 94.14; these are assigned, respectively, to C' and C2 of the vinylidene ligand. In