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First example of reversal of normal stereoselectivity in the intramolecular Pauson-Khand reaction

✍ Scribed by Joseph A. Casalnuovo; Robert W. Scott; Eric A. Harwood; Neil E. Schore


Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
314 KB
Volume
35
Category
Article
ISSN
0040-4039

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Absfrrrct 6-Cyclopropylidenel-hexynes like 2, e. g. prepared via palladium(O)-catalyzed substitution of l-ethenyl cyclopropyl sulfonates 1, undergo an intramolecular huson-Khand reaction both efficiently and regioselectively.